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991.
Wahyu Widada Hideki Kinjo Hiroaki Kuze Nobuo Takeuchi Makoto Sasaki 《Optical Review》2001,8(5):382-387
This paper describes the lidar inversion of the tropospheric aerosol extinction profiles under the influence of multiple-scattering effects for various elevation angles of lidar detection. A single-scattering lidar equation is employed to analyze lidar signals with multiple-scattering contributions that are calculated by the Monte Carlo method for given atmospheric conditions. We calculate errors in the optical thickness from the results with and without multiple-scattering effects. It is found that the errors vary in a range of 2#x2013;18#x0025; according to the optical thickness variation of 0.19#x2013;3.8. The dependence of the error on the field-of-view angle of the lidar observation is also discussed. 相似文献
992.
Shun‐ichi Matsuda Yoshiro Kaneko Jun‐ichi Kadokawa 《Macromolecular rapid communications》2007,28(7):863-867
An amylose‐grafted chitosan has been synthesized by a chemoenzymatic method according to the following two reactions. First, maltoheptaose is introduced to chitosan by a reductive amination using sodium cyanotrihydroborate in a mixed solvent of 1.0 mol · L−1 aqueous acetic acid and methanol at room temperature to produce a maltoheptaose‐grafted chitosan that has a well‐defined molecular structure. A phosphorylase‐catalyzed enzymatic polymerization of α‐D ‐glucose 1‐phosphate is then performed from the maltoheptaose‐grafted chitosan to obtain the amylose‐grafted chitosan. This material does not dissolve in any solvent, e.g., aqueous acetic acid and dimethyl sufoxide, which are good solvents for chitosan and amylose, respectively.
993.
A phenomenological model of the transition from quark-gluon phase to hadron phase is presented on the analogy of BCS theory. The massive current-quarks constitute the quark Cooper-pair, i.e., the hadron at Tc = 150~200 MeV, The order parameter of qq-pair takes a value in the range from 0.4 to 0.2 GeV. An experimental verification method of the present model in the heavy-ion collision is proposed. 相似文献
994.
995.
形变双奇核178Ir转动带能级的旋称反转 总被引:1,自引:0,他引:1
张玉虎 T.Hayakawa M.Oshima Y.Toh J.Katakura Y.Hatsukawa M.Matsuda N.Shinohara T.Ishii H.Kusakari M.Sugawara T.Komatsubara 《中国物理 C》2000,24(12):1123-1130
利用152Sm(31P,5nγ)178Ir反应产生并研究了双奇核178Ir的高自旋态.实验中进行了178Ir核的在束γ测量,包括γ射线的激发函数测量、X–γ和γ–γ符合测量.首次建立了双奇核178Ir基于πh9/2νi13/2和πh11/2νi13/2准粒子组态上的转动带能级纲图.发现在低自旋区,两个转动带能级均出现旋称反转.对此核区半退耦带的旋称反转作了简要的分析和讨论. 相似文献
996.
Tamiko Takahashi Hiroaki Kameda Tomoyo Kamei Jyunichi Koyanagi Fabio Pichierri Kenji Omata Miyuki Ishizaki Hiroshi Nakamura 《Tetrahedron: Asymmetry》2013,24(17):1001-1009
Optically active 1-fluoroindan-1-carboxylic acid (FICA) was designed and prepared as its methyl ester for determining the absolute configuration of chiral molecules by both 1H and 19F NMR spectroscopies. Enantiomerically pure isomers of FICA methyl esters (FICA Me esters) were obtained by chromatographic separation using HPLC with a Daicel Chiralcel OJ-H column. The absolute configuration of the (+)-FICA Me ester was deduced to be (S) by X-ray crystallographic analysis of the (+)-FICA amide of (R)-α-phenethylamine. Both enantiomers were derived to the diastereomeric esters of chiral secondary alcohols by an ester exchange reaction. In the 1H NMR spectra, the signs of ΔδH (δR ? δS) were consistent on each side of the FICA molecular plane. Therefore, the concept of the modified Mosher’s method could be successfully applied to the FICA-based procedure. Moreover, the consistency in the signs of ΔδF (δR ? δS) values suggests that the FICA method would be reliable in assigning the absolute configurations of secondary alcohols based on 19F NMR spectroscopy. 相似文献
997.
Hiroaki Yamaguchi Asuka Fujikawa Hajime Ito Nobuaki Tanaka Ayako Furugen Kazuaki Miyamori Natsuko Takahashi Jiro Ogura Masaki Kobayashi Takehiro Yamada Nariyasu Mano Ken Iseki 《Biomedical chromatography : BMC》2013,27(4):539-544
A column‐switching liquid chromatography/electrospray ionization tandem mass spectrometry to determine paclitaxel and its metabolites, 6α‐hydroxypaclitaxel and p‐3′‐hydroxypaclitaxel, in human plasma was developed. The analytical system had a Shim‐Pack MAYI‐ODS (10 × 4.6 mm i.d.) trapping column with deproteinization ability that concentrates analytes and removes water‐soluble components. This method covered a linearity range of 5–5000 ng/mL of concentrations in plasma for paclitaxel, a range of 0.87–870 ng/mL for 6α‐hydroxypaclitaxel and a range of 0.87–435 ng/mL for p‐3′‐hydroxypaclitaxel. The intra‐day precision and inter‐day precision of analysis were less than 11.1%, and the accuracy was within ±14.4% at concentrations of 5, 50, 500 and 5000 ng/mL for paclitaxel, 0.87, 8.7, 87 and 870 ng/mL for 6α‐hydroxypaclitaxel, and 0.87, 8.7, 87 and 435 ng/mL for p‐3′‐hydroxypaclitaxel. The total run time was 30 min. Our method was successfully applied to clinical pharmacokinetic investigation. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
998.
999.